简介:Ferrumniobatewassynthesizedbysolid-phasesinteringmethodinavacuumcarbontubefurnaceat1300℃for180min.ThephasetransformationofferrumniobatecarbothermalreductionprocesswasstudiedbyXRD.ThereductionreactionsofferrumniobateindifferenttemperaturestagesweredeterminedbytheTG-DSCcurve.Meanwhile,accordingtotheTGcurve,thereactionkineticsparameterswerecalculatedbyA.W.Coatsintegrationandthecontrolstepsindifferenttemperaturestageswereascertained.Theresultsshowedthatthereductionofferrumniobatestartsatthetemperatureof1000℃,andthereductionprocesscarriesoutintwostepsaccordingtosinteringtemperature.Inatemperaturerangeof1000-1238℃(thefirststep),themainreductionproductsareNbO2andFe;thekineticequationofinitialstageis[-ln(1-α)]4=kt,controlledbynucleationgrowth,andtheapparentactivationenergyis388kJ/mol;withthetemperatureincreasing,thekineticequationisα+(1-α)ln(1-α)=kt,whichistheValensitwo-dimensionaldiffusionkineticequation,andtheapparentactivationenergyis264.4kJ/mol.Themainreactioninarangeof1238-1344℃(thesecondstep)isthereductionofNbO2toNbC,thekineticequationis[(1-α)-1/3-1]2=kt,whichiscontrolledbythethree-dimensionaldiffusion,andtheapparentactivationenergyis482.7kJ/mol.
简介:三维的磨擦促使焊接(FSW)过程模型基于液体力学被开发了。在焊接过程的材料运输被认为是laminar,粘滞、非牛顿经过一根旋转大头针流动的液体。划分焊接地区的一个标准根据速度地和粘性地的合作被给了。也就是说,在工具大头针附近存在的0-easy-flow地区对应于焊接金块地区;在0-easy-flow地区和1粘性乐队之间的区域被通信到热机械的影响地区(TMAZ)。模型给一些有用信息通过速度分发的模拟结果在FSW改进材料流动的理解。为了估价磨擦,促使大头针设计,三种大头针几何学,一个人是列大头针,第二是逐渐变细大头针,和最后大头针是螺丝钉线程逐渐变细大头针,在模型被使用。大头针几何学严重在0-easy-flow地区影响了速度分发的模拟结果。在0-easy-flow地区的速度分发能被看作优化磨擦的标准搅动工具设计。这研究将受益指导磨擦搅动工具设计。
简介:Amodelwaspresentedtodescribethemicrostructureevolutionduringthedirectionalsolidificationprocess.Inthismodel,theproblemofdifferentpropertiesinthesolidandliquidphasewassolvedbymakingthepropertiescontinuousatthesolid/liquidinterface.Furthermore,arandomnoisewasincorporatedtoreflecttheanisotropicgrowth.Moreover,theaveragingsoluteconservationwasdevelopedtokeepthetotalsoluteconservationintheinterfaceregion.Asimpleingotwassimulatedbythismethod,themodelcanrepresentthemicrostructureevolution,soluteconcentrationredistribution,micro-segregationandthecolumnar-to-equiaxedtransition.
简介:CuSpinealmicrospherescongregatedfrominterleavingnanoflakeswiththicknessof40to200nmweresynthesizedbyapyridine-solvothermalprocessviathereactionbetweencupricchloride(CuCl2·2H2O)andthioacetamide(TAA,CH3CSNH2).TheproductswerecharacterizedbyX-raydiffractionandscanningelectronmicroscopy.UV-Visabsorptionspectrum,excitationandphotoluminescencespectraofCuSpinealmicrosphereswereobtainedatroomtemperaturetoinvestigatetheiropticalproperties.ApossiblegrowthmechanismontheformationofCuSpinealmicrospheresisproposed.ThefactorsinfluencingtheevolutionofmorphologiesofCuScrystalsincludingthedosageofthereactants,surfactant,andsulphur-sourcewerealsoanalyzed.
简介:Thepurposeofthisresearchistoquantifytheeffectsofcompositionalandprocessingparametersonthemicrostructureandpropertiesofdualphasesteelproduceddirectlybyhotrollingandrapidcooling.Steelswiththebasecompositionof0.1%C,1.4%Si,and1.0%Mnwithadditionsof0.5%Crtoinfluencehardenability,0.04%Nbtoretardrecrystallizationinthelatterstagesofrolling,or0.02%Titoinhibitgraingrowthduringandafterreheatingwereinvestigated.Investigationwasmadetopredictmicrostructureevolutionandtocorrelatemicrostructurewithprocessingparameters.Theeffectsoftheimportantmicrostructureparameterssuchasferritegrainsize,martensitevolumefraction(VM)andmorphology(polygonalorfibrous)onthetensileandimpactpropertiesarediscussed.Multiplelinearregressionanalysisoftheultimatetensilestrengthhasshownthat,increasingVMandmartensitemicrohardnessandgrainrefinementofferritearethemajorcontributionstoincreasethestrengthofthesteel.Itwasfoundthatthedual-phasesteelproducedbycontrolledrollingprocess,withamicrostructurewhichconsistedoffinegrainedferrite(4μm)and35%~40%fibrousmartensite,presentedoptimumtensileandimpactpropertiesbecauseofenhancedresistancetocrackpropagation.
简介:Amodelcombinedbothmacroscopictransportandmicrostructuralevolutionisappliedtodescribetheinfluenceofthermosolutalconvectiononmicrostructuralevolutionduringthesolidificationprocess.Firstly,thevolumeaveragemethodandSimpleralgorithmareusedtosolvethemacroscopictransportequation.Thenthecalculatedresultsareincorporatedintothecellularautomaton(CA)modeltosimulatethemicrostructuralevolution.Usingthismodel,asimplecastingingotisappliedtosimulatemicrostructuralevolution.Throughthesimulation,itisfoundthatthethermosolutalconvectionhasastronginfluenceontheredistributionoftemperaturefieldandsolutefield,whichinfluencethesolidificationmicrostructuralevolution.
简介:Sheetmetalformingiswidelyappliedtoautomobile,aviation,spaceflight,ship,instrument,andapplianceindustries.Inthispaper,basedonanalyzingtheshortcomingofgeneralfiniteelementanalysis(FEA),theconceptionofparametricfiniteelementanalysis(PFEA)ispresented.Theparametricfiniteelementanalysis,artificialneuralnetworks(ANN)andgeneticalgorithm(GA)arecombinedtoresearchthoroughlyontheproblemsofprocessparametersoptimizationofsheetmetalforming.Theauthorprogramstheoptimizationschemeandappliesitinaresearchofoptimizationproblemofinsidesquareholeflangingtechnologicalparameters.Theoptimizationresultcoincideswellwiththeresultofexperiment.Theresearchshowsthattheoptimizationschemeoffersagoodnewwayindiedesignandsheetmetalformingfield.
简介:Thehydrodynamicdeepdrawingprocessenablesnetshapeornearnetshapeformingofcomplicatedsheetmetalpartsmadefromdifficultlyformingmaterials,suchasaluminiumorhighstrengthsteels.Basedontheconventionalhydrodynamicdeepdrawingprocess,anewprocess,hydrodynamicdeepdrawingprocess,inwhichradialpressureisappliedtotherimoftheblank,isproposed.ThisnewprocesshasbeenanalysedusingFEMsimulationsandtheobtainedresultshavebeencomparedwiththeexperimentalresults.ThematerialusedintheexperimentswasAl-Mg-Sialloy,andintheFEM-simulationstheelastic-plasticbehaviourofAl-Mg-SialloywasmodelledusingBarlat's89yieldcriteria.
简介:Withtheaidofthelatestfiberopticsensingtechnology,parametersinthecureprocessofthermosettingresin-matrixcomposite,suchastemperature,viscosity,voidandresidualstress,canbemonitoredentirelyandefficiently.Inthispaper,experimentresultsofviscositymeasurementincompositecureprocessinautoclaveusingfiberopticsensorsarepresented.Basedonthesensedinformation,acomputerprogramisutilizedtocontrolthecureprocess.Withthistechnology,thecureprocessbecomesmoreapparentandcontrollable,whichwillgreatlyimprovethecuredproductsandreducethecost.
简介:AhypereutecticAl-Sialloypowderwaspreparedbyultrasonicgasatomizationprocess.Themorphologies,microstructureandphaseconstituentofthealloypowderwerestudied.TheresultsshowedthatpowderofthealloywasveryfineanditsrnicrostructurewasmainlyconsistedofSicrystalsplusintermetalliccompoundAl9FeSi3,whichwere.veryfineanduniformlydistributed.