简介:Novelcore-shellhydroxyapatite/chitosanbiocompositenanospheresweresynthesizedinamultipleemulsion.Themultipleemulsionwasaw/o/wemulsion,madeofdiammoniumphosphatesolutionasaninneraqueousphase,cyclohexaneasanoilphase,andcalciumnitratesolutionandchitosansolutionasanouteraqueous.Theformingmechanismofcore-shellspheresandtheinfluenceoftemperatureonthemorphologyofthenanosphereswereinvestigated.Thediameteroftheresultingcore-shellnanosphereswas100-200nmandthethicknessofthechitosanshellwasabout10nm.Anditconcludedthatatdifferentreactiontemperaturethemorphologiesoftheproductswouldbechanged.Thecore-shellnanosphereshavepotentialapplicationsforthedevelopmentofnewbiomedicalmaterials.
简介:Theindustrialmanufactureprocessesofthreekindsofrollcoreusedductileironshavebeeninvestigatedviasystematicalexperiments.EffectsoftheratioofC/Si,pigiron,nodularizerandalloyingmethodonthemicrostructureandmechanicalpropertiesoftheheavysectionductileironhavebeenanalyzed.IthasbeenfoundthatwhentreatedwithRE-MgplusSb,highqualitynodularcastingscanbeproducedevenifmuchantispheroidizingalloyelementsareincludedinthepigiron.ThealloyelementSbplayedanimportantroleinthecontrolofgraphitemorphology.
简介:Mechanicalpropertiesofepoxyresinwereinvestigatedbyaddingcore-shellelasticparticles(CSEP).Theresultsindicatedthatoptimizedcore-shellratiowas60/40andtheloadingvolumeofCSEPwas10phr(perhundredpartsofepoxyresinbyweight).Theimpactstrengthofmodifiedsystemsincreasedapparentlywiththedecreaseofcoresizes.However,theshearingstrengthchangedgentlywiththeparticlesizes.CSEPwithlightlycrosslinkedrubberycoreshowedmoreeffectivenessontoughnessthanothers.Withsolutionblending,CSEPcouldbedispersedinepoxymatrixwell,andthemorphologiesofdispersedrubberdomainswerecontrolledperfectlybyCSEPwhosestructurewaspredesigned.Acavitation-shearingbandtoughnessmechanismwasobservedfromtheSEMmicrographsoffracturesurface.Italsowasfoundthatthedeformingtemperature(DT)ofmodifiedepoxydidnotdeclineapparently.