简介:AmethodforremovimgglucorapheninfromtheextractofRadishpigmentbyanionexchangeresin201×7wasstudied.Theadsorptioncapacityof201×7resinforglucorapheninwas72.8mg/mlresin,theequilibriumtime55minutes,andtheoptinumpH5.5.Allglucorapheninthathadbeenadsorbedon201×7resinwaselutedby1.5BV.hr^-1,eluentinwhincconcentrationofNaOHwas0.05mol·L^-1attheflowrateof1.5BV/h.Extractingsolutionofdeglucorapheninwasenrichedbyvacuumandspraydrying.ApowderproductofRadishpigmentwasobtainedandE1cm^1%=4.30.
简介:Kineticsofchloride/sulfate,chloride/nitrateandnitrate/sulfateforwardexchangesandreverseexchangesatsolutionconcentrationsof1N,0.2Nand0.02Non201×7strongbaseanionexchangeresin,respectively,havebeenexaminedat25℃.Itisfoundthattheforwardandthereverseexchangeratesofthetwogivenionsatlowsolutionconcentration,respectively,underidenticalconditionscanbecontrolledbydifferentmechanisms,whilethoseathighsolutionconcentrationareallcontrolledbyparticlediffusion.Theternaryexchangeratesofsulfate/(chloride+nitrate)andnitrate/(chloride+sulfate)havealsobeenexamined.
简介:Dithia-monoaza18-Crown-6anditsimmobilizationproduct,silica-bound1,7-dithia-4-aza-10,13,16-trioxa-cyclooctadecaneviaaspacerofthreecarbonatoms,anditsplatinumcomplexhavebeensynthesized.Itisfoundthattheplatinumcomplexisanefficienthydrosilylationcatalystforolefins.TheXPSdataoftheplatinumcomplexarereported.