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48 个结果
  • 简介:送检地下水水型为HCO3^--SO4^2--Ca^2+-(Mg^2+)型,酸碱度为中性、水介质属氧化型(Eh=640my)、低矿化,样品水中各项水质分析项目为,K^++Na^+,Ca^2+,Mg^2+,Fe^3+,Cl^-,SO4^2-,HCO3^-,CO3^2-,NO3^-,OH^-;所对应分析值为0.670×10^-3,1.200×10^-3,0.400×10^-3,1.79×10^-3,0.036×10^-3,0.88×10^-3,2.074×10^-3,10^-5.863,0.035×10^-3,10^-7.07。

  • 标签: 地下水 Eh值 HCO3^- 应用 计算 析出
  • 简介:为了明确团聚现象及表面性质对ZnS纳米材料发光性质的影响,采用SiO2对ZnS材料进行了表面修饰,并对ZnS及ZnS/SiO2复合材料的光学性质进行对比研究。采用吸收光谱分析了包覆前后光吸收性质的差异,发现SiO2包覆后ZnS纳米材料的带边由333nm红移至360nm。为了研究ZnS纳米材料与ZnS/SiO2纳米复合材料的光发射性质,分别对含纳米材料的水溶液样品及粉末样品的发光光谱进行了采集。对比研究的结果表明,SiO2包覆后ZnS纳米材料在蓝紫光区的发光得到了明显增强。以氙灯作为激发光源所获得荧光光谱显示ZnS/SiO2粉末样品发光的积分强度增大为原来的17.5倍,但相同条件下针对溶液样品的测试结果显示其发光强度只增大了1.1倍,这种增强可用SiO2的存在抑制了ZnS纳米粒子间的团聚来解释,且这一推断由325nm紫外激光激发下获得的光致发光数据进行了验证。

  • 标签: 复合材料 ZnS/SiO2 发光 荧光增强
  • 简介:Variousagriculturalcropresiduesincludingcornstover,corncob,andsorghumstalkwithamoisturecontentof75wt%weresubjectedtoalongpretreatment(12-60h)withsupercriticalCO2(scCO2),atlowtemperature(50-80℃)andapressureof17.5-25.0Mpa.Thesugaryieldsfromtheenzymatichydrolysis(EH)ofthepretreatedsampleswereasmuchasthree-tofourfoldgreaterthanthoseaffordedbytherawmaterials.However,whenpretreatmentwasconductedwithinashorttime(e.g.0.5h),aspreviouslyreportedintheliterature,onlyaslightincreaseintheEHsugaryieldswasobserved.TheproposedscCO2pretreatmentmechanismdemonstratedtheroleofmoistureinthesystem.Wetting,softening,andswellingwereobservedtomainlyaffectthelignocellulosewhenasuitableamountofwaterwasadded.Finally,thesampleswereanalysedbyX-raydiffractionandscanningelectronmicroscopy,beforeandafterpretreatment,toinvestigatethechangesinthemicroscopicstructureofthebiomass.

  • 标签: LIGNOCELLULOSE scCO2 PRETREATMENT ENZYMATIC HYDROLYSIS SUGAR
  • 简介:K文件》这本有占奇怪的左图右文的书,是一群有点奇怪的K客玩出来的,K客是一群艺术玩家,他们几乎无所不玩,无所不玩而后快,他们提出的口号是:一、用自己的玩法去玩。二、人人都是艺术家。然后,他们使用PS、鼠标笔、某种奇怪的文字,各种随手物件和一个开窍的大脑,开始去K

  • 标签: 《K文件》 左图右文书 艺术家 网络 剂剑非
  • 简介:Inthisstudy,weattempttheanalysisofthepassageflowinthecentrifugalimpellerusingFEMwith/withouttheturbulencemodel,andcomparethisresultwiththeexperimentalresult.TheturbulencemodelisthelowReynoldsk-εmodelproposedbyChien.WeusetheGSMACmethodfortheReynoldsaveragedNavier-Stokesequations,theEulerexplicitmethodforthetransportequationsoftheturbulentkineticenergyandthedissipationrate.AllequationsarediscretizedbytheGalerkin'smethod.Atthemidpassageofthecentrifugalimpeller,thepassagewisevelocitycomponenttendstoincreaseinthepressure-to-suctiondirection,andtheothercomponenttowardthepressuresurfacetendstobelargeintheregionofthemiddleblade-to-bladetothehubside.Thetipleakagesappeararoundtheregionofthemiddleblade-to-bladenearthecasingtogetherwiththesecondaryflowtowardthesuctionsurface.Thesephenomenacorrespondwiththeexperimentalresult,qualitatively.

  • 标签: 离心叶轮机 流体流动分析 有限元法 叶片
  • 简介:In2010,theBESCollaboration[1]foundaclearenhancementintheK0K0massdistributionintheJ=ψ!ηK0K0decay.SuchanenhancementisusuallyasignatureofanL=0resonancearoundthreshold,whichinthiscasewouldcorrespondstoanh1statewithquantumnumbersIG(JPC)=0??(1+??).Thish1statewaspredictedbytheChiralUnitarytheoryintheKKinteraction.Becauseoftheconversationlaw,thisstatecanonlydecaytoK0K0channel,andcanbestudiedefficientlyintheJ=ψ!ηK0K0decay.

  • 标签: SIGNATURE SIGNATURE QUANTUM CLEAR can BES
  • 简介:Mixedalcoholisofgreatpromiseasoctaneimproverinautomotivefuel,andhopefultoreplacetheMTBEtoreducetheenvironmentalpollution,Inthisfield,alkali-promtedmolybdenum-basedcatalystshavebeengivenspecialinterestbecauseoftheirexcellentsulfur-toleranceforsynthesisofmixedalcoholfromCO+H2,Itwasreportedthatthecoblatisafavorablepromoterforenhancingalcoholproduction,especiallyforimprovingtheselectivityforC2+alcohol[1-3],moreover,stronginteractionbetweenConandMoisinfavorofmixedalcoholsynthesis[4].Recently,weprparedakindofK-Co-Moultrafineparticlesbysol-gelmethodanditshowsmuchsmallerparticlesizebuthigheractivtyandselectivitytowardalcoholformationthantheonepreparedbyconventionalmethod[5],TheaimofthepresentworkistoresearchthemicostructuresoftheMoandCospeciesintheK-Co-Mosamplespreparedbydifferentmethod.

  • 标签: K-Co-M样品 微结构 EXAFS实验
  • 简介:为验证CO_2探测仪光学设计的合理性和可行性,采用单通道模拟样机,利用太阳光加漫反射板模式对大气光谱进行实验测试,并在实验室对单通道模拟样机进行光谱定标。利用光谱配准算法对两种方法得出的谱线位置进行匹配计算,结果表明:在吸收线深度稳定位置的配准峰值点偏差小于0.006nm,满足算法的精度要求。此种方法不仅验证了匹配算法的有效性,也验证了光学系统设计的合理性和可行性,为以后的光谱仪设计提供了理论与实验数据。

  • 标签: 探测仪 单通过光学系统 漫反射板 光谱配准
  • 简介:Anovelgas-phaseelectrocatalyticcellcontainingalow-temperatureprotonexchangemembrane(PEM)wasdevelopedtoelectrochemicallyconvertCO2intoorganiccompounds.TwodifferentCu-basedcathodecatalysts(CuandCu-C)werepreparedbyphysicalvapordepositionmethod(sputtering)andsubsequentlyemployedforthegas-phaseelectroreductionofCO2atdifferenttemperatures(70-90℃).ThepreparedelectrodesCuandCu-CwerecharacterizedbyX-raydiffraction(XRD),X-rayphotoemissionspectroscopy(XPS)andscanningelectronmicroscopy(SEM).Asrevealed,CuispartiallyoxidizedonthesurfaceofthesamplesandtheCuandCu-Ccathodiccatalystswerecomprisedofaporous,continuous,andhomogeneousfilmwithnanocrystallineCuwithagrainsizeof16and8nm,respectively.Theinfluenceoftheappliedcurrentandtemperatureontheelectro-catalyticactivityandselectivityofthesematerialswasinvestigated.Amongthetwoinvestigatedelectrodes,thepureCucatalystfilmshowedthehighestCO2specificelectrocatalyticreductionratesandhigherselectivitytomethanolformationcomparedtotheCu-Celectrode,whichwasattributedtothehigherparticlesizeoftheformerandlowerCuO/Curatio.Theobtainedresultsshowpotentialinterestforthepossibleuseofelectrical「enewableenergyforthetransformationofCO2intovaluableproductsusinglowmetalloadingCubasedelectrodes(0.5mgCucm2)preparedbysputtering.

  • 标签: C02 VALORIZATION ELECTRO-REDUCTION CU catalyst PEM
  • 简介:Inthiswork,MoOxpromotedIr/SiO2catalystswerepreparedandusedfortheselectivehydrogenolysisoftetrahydrofurfurylalcohol(THFA)to1,5-pentanediolinacontinuousflowreactor.Theeffectsofdifferentnoblemetals(Ir,Pt,Pd,Ru,Rh),supportsandIrcontentswerescreened.Amongtheinvestigatedcatalysts,4wt%Ir-MoOx/SiO2withaMo/Iratomicratioof0.13exhibitedthebestcatalyticperformance.ThesynergybetweenIrparticlesandthepartiallyreducedisolatedMoOxspeciesattachedonthemisessentialfortheexcellentcatalyticperformanceofIr-MoOx/SiO2.ThecatalystexhibitedabetterhydrogenolysisefficiencyofTHFAwiththeselectivityof1,5-pentanediolof65%–74%ataconversionofTHFAof70%–75%whentheinitialTHFAconcentrationisrangingfrom20wt%and40wt%.AndhighersystempressurewasalsoinfavoroftheconversionofTHFA.Duringastabilitytest,theconversionofTHFAand1,5-pentanediolyieldoverIr-MoOx/SiO2decreasedwithreactiontime,whichcanbeexplainedbytheleachingofMospeciesduringthereaction.

  • 标签: 戊二醇 催化剂 SiO 化学选择性 氢解 四氢糠基
  • 简介:Ingasturbineengines,laminar-turbulenttransitionoccurs.However,generally,theturbulencemodelstodescribesuchtransitionresultsintooearlyandtooshorttransition.Combiningaturbulencemodelwithadescriptionofintermittency,i.e.thefractionoftimetheflowisturbulentduringthetransitionphase,canimproveit.Bylettinggrowtheintermittencyfromzerotounity,startandevolutionoftransitioncanbeimposed.Inthispaper,amethodwhereadynamicequationofintermittencycombiningwithatwo-equationk-ωturbulencemodelisdescribed.Thisintermittencyfactorisapremultiplicatoroftheturbulentviscositycomputedbytheturbulencemodel.FollowingasuggestionbyMenteretal.[1],thestartoftransitioniscomputedbasedonlocalvariables.

  • 标签: BYPASS TRANSITION intermittency SST TURBULENCE model.
  • 简介:Catalyticpropertiesofthemetal-organicframeworkCr-MIL-101insolvent-freecycloadditionofCO2toepoxidestoproducecycliccarbonatesusingtetrabutylammoniumbromideasco-catalysthavebeenexploredundermildreactionconditions(8barCO2,25C).Styreneandpropylenecarbonateswereformedwithhighyields(95%and82%,respectively).CatalyticperformanceofCr-MIL-101wascomparedwithotherMOFs:Fe-MIL-101,Zn-MOF-5andHKUST-1.Thecatalyticpropertiesofdifferentquaternaryammoniumbromides,Cr-MIL-101aswellasPW12/Cr-MIL-101compositematerialhavebeenassessedinoxidativecarboxylationofstyreneinthepresenceofbothtert-butylhydroperoxideandH2O2asoxidantsat8100barCO2and2580Cwithselectivitytostyrenecarbonateupto44%at57%substrateconversion.

  • 标签: 环状碳酸酯 环氧化物 金属有机 季铵盐 催化合成 框架
  • 简介:Thenextgenerationofadvancedlightsourcesrequiresphotonswithlargeaveragefluxandhighbrightness,whichneedsadvancedelectrongunmatchedwithexcellentphotocathodematerials.K2CsSbphotocathodehastheadvantagesofhighquantumefficiency,longlifetimeandinstantaneousresponse.ThisstudyintroducesthedesignofasetofK2CsSbphotocathodepreparationsystemsanddetailedpreparationprocessofK2CsSbphotocathodes,includingsequentialdepositionprocessandco-depositionprocess,andfinallydevelopsaK2CsSbphotocathode.Theinfluenceoflaserpoweronthequantumefficiencyisalsoinvestigated.

  • 标签: CS SB St DEVELOPMENT of PREPARATION