简介:Melt-spunribbonswhicharetheimportantrawmaterialforhot-deformedmagnetscanbepreparedbysingle-rollermelt-spinning.Inordertopreparewell-structuredribbons,themodeloftemperaturefieldforsingle-rollermelt-spinningprocesswasconstructedinthiswork.Theheatconductioninthisprocesswassimplifiedasonedimensionalheatconductionproblem.Itwasshownbymodelingthat,thetemperaturefieldinthemelt-spinningbeforesolidificationinthismodelcouldbedescribedasthisequationT(x,t)=Tmoexp[–k(x–x0)–k2αt]+T0.ThetemperatureT(x,t)ofthealloymeltsdecreasedwithincreasedpositionxandcoolingtimetexponentiallyfromthewheel-freesurfacetothewheel-sidesurface.TheconstantkdeterminedthedecreasespeedofalloytemperatureT(x,t),whichwasproportionaltotheinterfacialheattransfercoefficienthandtheinterfacialareaofheatconductionA0,butinverselyproportionaltothethermalconductivityK.x0wasthethicknessofthealloymelt.Withincreasedx0,thetemperaturedifferencebetweenwheel-freesurfaceandthewheel-sidesurfacebecamelarger,whichwouldleadtolargerdifferenceingrainsize.Inexperiments,theinfluenceofmelt-spinningprocessparametersonthetemperaturefieldmodelwasdiscussed,suchascoolingrollermaterials,wheelspeed,andsoon.Melt-spunribbonspreparedbysingle-rollermeltspinningatdifferentwheelspeedwereinvestigatedandmagneticpropertiesofdie-upsetmagnetsfrommelt-spunribbonsondifferentcoolingrollerwereanalyzed.Thevariationofgrainsizeinthedepthdirectionconsistedwithtemperaturefieldmodel.Thismodelprovideddirectionsforthepreparationofmelt-spunribbonswithuniformlydistributedfinegrains,whichwereverynecessaryforproducinghot-deformedmagnetswithhighmagneticperformance.
简介:Thesimplemodelfor4f-5dtransitionsoflanthanideionsincrystalswasextendedtodealwiththecaseoftheoctahedralcrystalfield,whereforthet2componentof5dorbitalsthespin-orbitinteractioncouldnotbeneglectedduetoincompletequenchingofthe5dorbitalangularmomentum.Theenergylevelsforthe4fN-15dconfigurationandtherelativelinestrengthsforthe4fN4fN-15dtransitionwerecalculatedindetail.Theresultwasappliedtotheinterpretationofthelow-temperature4f-5dexcitationspectrumofCs2NaYCl6∶Tb3+.