简介：OnNovember29,2013theShaanxiCoalChemicalsTechnologyEngineeringCenter,Ltd.(SCCTEC),theCNOOCHuizhouRefiningandChemicalCompanyandtheSINOPECLuoyangEngineeringCompany,Ltd.signedanagreementoncooperationindevelopmentofan

简介：Theneedforcleanerfuelshasresultedinacontinuingworldwidetrendtoreducedieselsulfurandaromatics.Therearemanyapproachestoreducingsulfurandaromaticsindiesel.Mostofthemhaveacommondrawbackofhighcostbecauseofadoptingtwostagesofhydrotreatingandusingnoble-metalcatalyst,especiallyforreducingaromatics.TheattempttoresolvethisissuehasledtotherecentdevelopmentoftheSingleStageHydrotreating(SSHT)processbyResearchInstituteofPetroleumProcessing(RIPP),SINOPEC.TheSSHTprocessisasingle-stagehydrotreatingtechnologyforproducinglowsulfurandlowaromaticsdiesel.Theprocessusesoneortwonon-noble-metalcatalystssystemandoperatesatmoderatepressure.Whenrevampinganexistingunittomeetlowaromaticsdieselspecification,theonlythingtodoistoaddareactororreplacetheexistingreactor,Inpilotplanttests,theSSHTtechnologyhassuccessfullytreatedSRGO(StraightRunGasOil),LCO(LightCycleOil)ortheblendofthem.ItisshownthatbyusingtheSSHTprocessdieselwithsulfurof30ppmandaromaticsof15m%canbeproducedfromMiddle-EastSRGOanddieselwitharomaticscontentof25m%canbeproducedfromcrackedfeed,suchasFCC-LCO.Highdieselyieldandcetanenumbergain(fromcrackedfeedstocks)givetheSSHTtechnologyaperformanceadvantagecomparedtoconventionalhydrocrackingandhydrotreatingprocesses.Thelowerinvestmentandoperatingcostisanotheradvantage.ThefirstcommercialapplicationoftheSSHTtechnologyhasbeeninoperationsinceSeptember2001.

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简介：Therestrictiononsulfurlevelingasolinehasbeenincreasinglytightened.TheU.S.TierⅡregulationrequiresareductionfromaverage340ppmto30ppmfrom2004to2008.Recentlysignificantprogresshasbeenmadeineffectivehighsulfurremoval,suchasposttreatmentofFCCgasolinebyselectivehydrotreating,SZorbsulfurremovaltechnology,OATSprocessetc.ThesulfurcontentofFCCgasolinecanbedeceasedtolessthan10ppm.WithregardtogasolinepoolcompositioninChina,itisveryimportanttolookforeffectivedesulfurizationprocessesthataresimple,straightforward,withlesshydrogenconsumption.Post-treatmentofFCCgasolineisapreferredoption.Fromthepointofviewofcomprehensiveutilization,alkylation,polymerization,isomerisationetc.canbeaddedtodesulfurizationprocesstomeettherequirementofultralowsulfur,premium.

简介：Thepowderedactivatedcarbontreatment(PACT)processhasbeenwidelyusedinmanyindustrialfields,however,veryfewPACTprocessesarebuiltforpetrochemicalwastewatertreatmentinChina.AnindustrialPACTunitlaunchedinapetrochemicalplantwasintroducedandevaluatedfromboththepracticeandmechanismstudy.Practically,thePACTprocessshowedexcellentcapabilityinpollutantsremoval,shockresistance,toxicitytolerance,andtheCODandammonium-NineffluentofPACTunitassistedbyPACwasequalto15.5mg/Land0.7mg/LlowerthanthatwithoutPACaddition,respectively.ThewetoxidationregenerationunitwasquiteefficientinsupplyingregeneratedPAC,and,however,thehardcalciumsulphatescaleandthehighpollutantconcentrationsolutionneededtobecarefullycontrolled.Moreover,althoughthecarbonbalanceshowedthattheadsorptioncapabilityofregeneratedPACwasnegligible,thebiologicaltestsprovedthattheregeneratedPACincreasedmicrobeactivityupto17%morethanpureactivatedsludgesystem,whichwasalmostcompatiblewiththefreshactivatedcarbon.

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简介：Thedensityofasphaltwasmeasuredwiththepycnometeranddensitometer.Creeppropertiesoftheasphaltwereinvestigatedwiththebendingbeamrheometerattemperaturesrangingfrom0℃to-36℃.Theasphaltdensitydatausedtocorrelatewiththecreeppropertieswerecalculatedfromtheregressionequationofdensityandtemperature.TheasphaltsampleusedtodeterminethecreeppropertywasagedbythestandardRTFOTtestandthePAVtest.Thetestresultsshowedthattheasphaltdensityhadalinearrelationshipwithtemperaturechanges.Thelogarithmofthecreepstiffnessandtheslopeofthelogarithmofthestiffnessat60secondsalldemonstratedalinearrelationshipwiththedensity,andtheregressioncoefficientofthesedatawasaround0.99.Thecreepstiffnessandtheslopeofthecreepstiffnesscanbecalculatedfromtheasphaltdensityatthesametemperature.

简介：根据催化裂开的产品分发的分析和解释基于高酸粗略，为石油酸的去碳酸基的机制在FCC过程期间被讨论。质子从地点能与更否定的费用与羰基组的氧相结合形成能在弱契约受到劈开的反应中介的Bronsted酸发源，导致从它形成烷基的分解跟随的羧基的酸的羧基的组碎三坐标的carbenium离子，公司和H2O。象一个electrophilic试剂罐头酸的吊楔从羧基的酸的羧基的组到随后释放CO2。

简介：ThesinteringofPtnanoparticlesisoneofthemainreasonsforcatalystdeactivationduringthehigh-temperaturepropanedehydrogenation(PDH)reaction.Promotersandsupportshavebeenintroducedtoprolongthecatalystlife.However,itisstillnecessarytodevelopnovelcatalystswithrobuststability.Herein,thephosphorus-modifiedcarbonnanotube-supportedPtnanoparticleswereemployedforthePDHprocess.PhosphorusmodificationimprovesthePtdispersion,effectivelypromotingtheactivityofPt/P-CNTs.Additionally,thephosphorus-modifiedCNTscaninteractstronglywithPtnanoparticlesbyimprovingtheelectrontransferorhybridization,stabilizingPtnanoparticlesfromagglomeration,andsignificantlyenhancingthecatalyststability.

简介：ChinaLihuayiGrouphasselectedtheLPOxo~(SM)SELECTOR~(SM)(low-pressurebutanol/octanol)technologyjointlylicensedbyDowChemicalCompanyandDavyPro-cessTechnologyLimitedtobeusedonitsnew250kt/aunit.ThisunitislocatedinDongyingcity,Shandongprov-incewithadesigncapacityratedat140kt/aoctanol,85kt/an-butanoland24.4kt/aiso-butanol,andtheconstruc-tionofthisunitisexpectedtobecompletedby2010.

简介：Threenewcatalystsbasedonthesilicagelsupportedpolyetherionicliquids(ILs),i.e.,[HO-PECH-MIM]Cl-Si,[H2N-PECH-MIM]Cl-Si,and[HOOC-PECH-MIM]Cl-Si,wereprepared,andtheirchemicalstructureswerecharacterizedbyinfrared(IR)spectroscopyandnuclearmagneticresonance(NMR)spectroscopy.Thermogravimetricanalyzer(TG),X-raydiffractometer(XRD)andscanningelectronmicroscope(SEM)wereusedtoevaluatetheirthermalstability,crystallinestructureandapparentmorphology,respectively.SurfaceareasofthepreparedcatalystswerecalculatedbytheBrunauer-Emmett-Teller(BET)method.Thecatalyticreactionforthesynthesisofpropylenecarbonate(PC)usingCO2andpropyleneoxide(PO)inthepresenceofthepreparedcatalystswasstudied.Theinfluencesoftimesofrecyclingandcatalyststructureoncatalyticperformancewerealsoinvestigated.TheexperimentalresultsshowedthatthesilicagelsupportedpolyetherILscatalystssuccessfullypreparedundermildconditioncouldpossesstheadvantagesofhighactivity,excellentthermalstability,goodselectivityandeasyrecycling,whilethephasetransitionoftheliquidpolyetherILscatalystswasalsoachieved.Whenthereactiontemperaturewas90°C,theCO2pressurewas2.0MPaandthedosageofthecatalystwas2.5%,[HOOC-PECH-MIM]Cl-Siwasfoundtohavethebestcatalyticperformanceinthecatalyticprocess,withtheconversionratereaching100%andtheselectivityequatingto98.2%.Theconversionrateandselectivitystillcouldreachmorethan90%evenafterthecatalystwasreusedfor15times.

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简介：TheRHTtechnologyandthesecondgenerationRHTcatalystswereappliedindesignofan1.7Mt/aVRDSunitattheSINOPECChanglingBranchCo.ThecommercialapplicationresultdemonstratedthattheRHTcatalystsshowedgoodactivityandstabilityinprocessinglow-sulfurandhigh-nitrogenresidue.ThefirstlongperiodrunofunitforprocessinghighFeandhighCacontentresiduewasachieved.ThereasonsforexcessivepressuredropofR-101wereascribedtoFeandCadepositionaswellascokeformation.

简介：Inthisstudy,themainfactorsinfluencingthemeasurementsbymeansoftheoff-linelow-field1HNMRinthelabwerediscussedbaseonarobustcalibrationmodelestablishedbythePLSalgorithmusing255crudeoilsamples.Thepreheatingtemperaturehadagreatinfluenceontheviscosityofoilsamplesandtheresolutionofspectralanalysis.Therepeatabilityofspectralmeasurementswasimpactedbythemetalandwaxcontentoftheoilsamples.Forthecaseofhighwaxcontentoils,thewaxspeciesbegantocrystallizeinthecourseofdeterminationthatcouldaffecttherepeatabilityofspectralmeasurements.ThesefactorshaveevidencedwhythepreheatingdevicesandfilterunitarenecessarywhenlowfieldNMRsystemisusedintheonlineanalysisprocess.Theinvestigationisveryimportantfortheon-lineapplicationofthelowfieldNMR.

简介：TheGCtypeaxiallow-pressuremethanolsynthesistowerdevelopedbyNanjingGuochangChemicalEngineeringCompanyhadpassedappraisalorganizedbyChinaPetroleumandChemicalSociety.Thistechnologyhasbeenfirstsuccessfullyappliedonthe50kt/alow-pressuremethanolunitoperatedbyShandongJiutaiChemicalTechnologyCompany,

简介：ThefirstinChinacommercialtestunitformanufactureofsyntheticnaturalgas(SNG)throughlow-temperaturemethanationofcokeovengasratedat5000m3/dhascompletedits1000-hourcontinuoustestsattheTongshidaCokeryinShanxiprovince.Itislearnedthatthewholeprocesstechnologyisthefirstinnovativeprojectrealized

简介：Nickel-basedcatalyst[N,N]NiBr2,inwhich[N,N]standsforN-(2,6-diisopropylphenyl)pyridine-2-carboxaldimine,showshighactivityforethylenepolymerizationinthepresenceoforganoaluminumcompoundsunderhighethylenepressuretoyieldpolyethylenecharacteristicoflowmolecularweightandhighlybranchedchains.Tolueneasthesolventismoreinfavorofcatalystactivity,highermolecularweightandbranchedchainsinpolyethylenestructureascomparedtohexanesolvent.

简介：TheJJDlow-pressureconstant-temperaturesuspendertubularmethanolsynthesissystemdevelopedbytheAnchunHighandNewTechnologyLimitedLiabilityCompanyhasitsapparentadvantageinenergyconservation.Itissaidthatthistechnologyistheinnovativeonebothat

简介：Inthisstudy,titaniumdioxidesupportedbymulti-walledcarbonnanotubes(MWCNTs/TiO2)andCr-dopedTiO2supportedbyMWCNTs(MWNTs/Cr-TiO2)weresynthesizedbythesol-gelmethod.Thepreparedsampleswerecharacterizedbytransmissionelectronmicroscopy,X-rayphotoelectronspectroscopy,X-raydiffraction,theBrunauerEmmett-Telleranalysis,andtheRamanspectroscopy.TheoxidationandefficiencyforremovalofSO2inasimulatedfluegaswereinvestigatedexperimentallyinafixed-bedreactor.The15%MWCNTs/Cr-Ti02sampledisplayedexcellentadsorptionproperties,andaSO2removalrateequatingto30.4151mg/gfromthesimulatedfluegascontaining2300μg/gofSO2,8%of02,and5%ofH20wasachievedunderoptimalconditionscoveringatemperatureof333.15K,andaspacevelocityof1275h^-1.TheadsorptionprocesswasenhancedbecauseCrdopingmodifiedtheporestructureandinhibitedthegraingrowthofTiO2.Inaddition,theFreundlichandLangmuirmodelsrevealedthatSO2wasmainlyadsorbedthroughchemicaladsorptiononthesamplesurfaces,andthethermodynamicmodelanalysisindicatedthattheadsorptionwasaspontaneous,exothermic,andentropy-reducingprocess.TheadsorptionkineticsofSO2canbedescribedbythepseudosecond-orderkineticandtheBanghamdynamicsmodels.Thepossiblereactionmechanisminvolvedindesulfurizationprocesswasalsoproposed.