简介:Theneedforcleanerfuelshasresultedinacontinuingworldwidetrendtoreducedieselsulfurandaromatics.Therearemanyapproachestoreducingsulfurandaromaticsindiesel.Mostofthemhaveacommondrawbackofhighcostbecauseofadoptingtwostagesofhydrotreatingandusingnoble-metalcatalyst,especiallyforreducingaromatics.TheattempttoresolvethisissuehasledtotherecentdevelopmentoftheSingleStageHydrotreating(SSHT)processbyResearchInstituteofPetroleumProcessing(RIPP),SINOPEC.TheSSHTprocessisasingle-stagehydrotreatingtechnologyforproducinglowsulfurandlowaromaticsdiesel.Theprocessusesoneortwonon-noble-metalcatalystssystemandoperatesatmoderatepressure.Whenrevampinganexistingunittomeetlowaromaticsdieselspecification,theonlythingtodoistoaddareactororreplacetheexistingreactor,Inpilotplanttests,theSSHTtechnologyhassuccessfullytreatedSRGO(StraightRunGasOil),LCO(LightCycleOil)ortheblendofthem.ItisshownthatbyusingtheSSHTprocessdieselwithsulfurof30ppmandaromaticsof15m%canbeproducedfromMiddle-EastSRGOanddieselwitharomaticscontentof25m%canbeproducedfromcrackedfeed,suchasFCC-LCO.Highdieselyieldandcetanenumbergain(fromcrackedfeedstocks)givetheSSHTtechnologyaperformanceadvantagecomparedtoconventionalhydrocrackingandhydrotreatingprocesses.Thelowerinvestmentandoperatingcostisanotheradvantage.ThefirstcommercialapplicationoftheSSHTtechnologyhasbeeninoperationsinceSeptember2001.
简介:Therestrictiononsulfurlevelingasolinehasbeenincreasinglytightened.TheU.S.TierⅡregulationrequiresareductionfromaverage340ppmto30ppmfrom2004to2008.Recentlysignificantprogresshasbeenmadeineffectivehighsulfurremoval,suchasposttreatmentofFCCgasolinebyselectivehydrotreating,SZorbsulfurremovaltechnology,OATSprocessetc.ThesulfurcontentofFCCgasolinecanbedeceasedtolessthan10ppm.WithregardtogasolinepoolcompositioninChina,itisveryimportanttolookforeffectivedesulfurizationprocessesthataresimple,straightforward,withlesshydrogenconsumption.Post-treatmentofFCCgasolineisapreferredoption.Fromthepointofviewofcomprehensiveutilization,alkylation,polymerization,isomerisationetc.canbeaddedtodesulfurizationprocesstomeettherequirementofultralowsulfur,premium.
简介:Thedensityofasphaltwasmeasuredwiththepycnometeranddensitometer.Creeppropertiesoftheasphaltwereinvestigatedwiththebendingbeamrheometerattemperaturesrangingfrom0℃to-36℃.Theasphaltdensitydatausedtocorrelatewiththecreeppropertieswerecalculatedfromtheregressionequationofdensityandtemperature.TheasphaltsampleusedtodeterminethecreeppropertywasagedbythestandardRTFOTtestandthePAVtest.Thetestresultsshowedthattheasphaltdensityhadalinearrelationshipwithtemperaturechanges.Thelogarithmofthecreepstiffnessandtheslopeofthelogarithmofthestiffnessat60secondsalldemonstratedalinearrelationshipwiththedensity,andtheregressioncoefficientofthesedatawasaround0.99.Thecreepstiffnessandtheslopeofthecreepstiffnesscanbecalculatedfromtheasphaltdensityatthesametemperature.
简介:ChinaLihuayiGrouphasselectedtheLPOxo~(SM)SELECTOR~(SM)(low-pressurebutanol/octanol)technologyjointlylicensedbyDowChemicalCompanyandDavyPro-cessTechnologyLimitedtobeusedonitsnew250kt/aunit.ThisunitislocatedinDongyingcity,Shandongprov-incewithadesigncapacityratedat140kt/aoctanol,85kt/an-butanoland24.4kt/aiso-butanol,andtheconstruc-tionofthisunitisexpectedtobecompletedby2010.
简介:TheRHTtechnologyandthesecondgenerationRHTcatalystswereappliedindesignofan1.7Mt/aVRDSunitattheSINOPECChanglingBranchCo.ThecommercialapplicationresultdemonstratedthattheRHTcatalystsshowedgoodactivityandstabilityinprocessinglow-sulfurandhigh-nitrogenresidue.ThefirstlongperiodrunofunitforprocessinghighFeandhighCacontentresiduewasachieved.ThereasonsforexcessivepressuredropofR-101wereascribedtoFeandCadepositionaswellascokeformation.
简介:Inthisstudy,themainfactorsinfluencingthemeasurementsbymeansoftheoff-linelow-field1HNMRinthelabwerediscussedbaseonarobustcalibrationmodelestablishedbythePLSalgorithmusing255crudeoilsamples.Thepreheatingtemperaturehadagreatinfluenceontheviscosityofoilsamplesandtheresolutionofspectralanalysis.Therepeatabilityofspectralmeasurementswasimpactedbythemetalandwaxcontentoftheoilsamples.Forthecaseofhighwaxcontentoils,thewaxspeciesbegantocrystallizeinthecourseofdeterminationthatcouldaffecttherepeatabilityofspectralmeasurements.ThesefactorshaveevidencedwhythepreheatingdevicesandfilterunitarenecessarywhenlowfieldNMRsystemisusedintheonlineanalysisprocess.Theinvestigationisveryimportantfortheon-lineapplicationofthelowfieldNMR.
简介:TheGCtypeaxiallow-pressuremethanolsynthesistowerdevelopedbyNanjingGuochangChemicalEngineeringCompanyhadpassedappraisalorganizedbyChinaPetroleumandChemicalSociety.Thistechnologyhasbeenfirstsuccessfullyappliedonthe50kt/alow-pressuremethanolunitoperatedbyShandongJiutaiChemicalTechnologyCompany,
简介:ThefirstinChinacommercialtestunitformanufactureofsyntheticnaturalgas(SNG)throughlow-temperaturemethanationofcokeovengasratedat5000m3/dhascompletedits1000-hourcontinuoustestsattheTongshidaCokeryinShanxiprovince.Itislearnedthatthewholeprocesstechnologyisthefirstinnovativeprojectrealized
简介:Nickel-basedcatalyst[N,N]NiBr2,inwhich[N,N]standsforN-(2,6-diisopropylphenyl)pyridine-2-carboxaldimine,showshighactivityforethylenepolymerizationinthepresenceoforganoaluminumcompoundsunderhighethylenepressuretoyieldpolyethylenecharacteristicoflowmolecularweightandhighlybranchedchains.Tolueneasthesolventismoreinfavorofcatalystactivity,highermolecularweightandbranchedchainsinpolyethylenestructureascomparedtohexanesolvent.
简介:OnNovember29,2013theShaanxiCoalChemicalsTechnologyEngineeringCenter,Ltd.(SCCTEC),theCNOOCHuizhouRefiningandChemicalCompanyandtheSINOPECLuoyangEngineeringCompany,Ltd.signedanagreementoncooperationindevelopmentofan