学科分类
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1 个结果
  • 简介:Methyl3-hydroxypropanoatewassynthesizedviahydroesterificationofethyleneoxidewithCOinthepresenceofdicobaltoctacarbonylcatalystandmethanolsolvent.Thecatalystexhibitedhighcatalyticactivity.Theeffectofreactiontemperature,COpressure,methanoldosage,catalystdosageandreactiontimeoncatalyticreactionwasinvestigated.Thetestresultsrevealedthatthisreactionwasgreatlyaffectedbyreactiontemperature,butitwasnotsignificantlyaffectedbytheCOpressure,themethanoldosage,thecatalystdosageandthereactiontime.Undertheoptimalconditions,theconversionofethyleneoxidewasequalto92.24%,whiletheselectivityandyieldofmethyl3-hydroxypropanoatereached88.99%and84.35%,respectively.

  • 标签: 钴催化剂 环氧乙烷 羰基 羟基 合成 阳离子