简介:ThecokedepositiononHZSM-5/SAPO-34compositecatalystshasbeenstudiedintheconversionofethanoltopropylene.TheHZSM-5/SAPO-34compositecatalystsweresynthesizedbyhydrothermalmethod(ZS-HS)andfullyblending(ZS-MM).TheusedcatalystswerecharacterizedbyXRD,N2adsorption–desorption,TGA,TPO,elementalanalysis,FTIRandXPS.ThecokingkineticsonbothZS-HSandZS-MMhasbeeninvestigatedandtheircokingrateequationswereobtained.TheusedZS-MMcatalysthadhigheramountofcokeandlowernC:nHthantheusedZS-HS.90%ofthecokewasdepositedinthemicroporesofZS-HS,whilealmost45%ofthecokelocatedinthemicroporesofZS-MM.ThecokedepositedonZS-HScatalystwasmainlygraphite-likecarbonspecies,whereasdehydrogenatedcokespecieswasthemajoronZS-MM.ThecokingactivationenergyofZS-MMwaslowerthanthatofZS-HS,andthecokingrateonZS-MMwasfasterthanonZS-HS.Inaddition,theregenerationofZS-MMcatalystshowedthatithadagoodhydrothermalstability.Thedifferencesoncokingbehaviorsonthetwocatalystswereduetotheirdifferentacidicpropertiesandtextures.