简介：Halfsandwichirondicarbonylcomplex[η5-C5H3(t-Bu)2]Fe(CO)2Cl(1)reactswith1,2-dilithiumdiselenocarboraneLi2Se2C2B10H10(2)togiveabinuclearironcarboranecomplex[η5-C5H3(t-Bu)2]2Fe2(CO)3*Se2C2B10H10(3).TheX-raydiffractionanalysisofcomplex3revealsthatoneoftheironatomsischiral.
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![Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex [η5-C5H3(<b style='color:red'>t</b>-Bu)<b style='color:red'>2</b>]<b style='color:red'>2</b>Fe<b style='color:red'>2</b>(CO)3Se<b style='color:red'>2</b>C<b style='color:red'>2</b>B10H10](/image/thesis0 "Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex [η5-C5H3(<b style='color:red'>t</b>-Bu)<b style='color:red'>2</b>]<b style='color:red'>2</b>Fe<b style='color:red'>2</b>(CO)3Se<b style='color:red'>2</b>C<b style='color:red'>2</b>B10H10")