简介：Thetime-of-flightmassspectrum(TOFMS)relativetotheresonanttwo-photonionizationofgasphasep-dichlorobenzenewasobtainedinthewavelengthrangeof240-250nmbyahome-madesystem.Aspecialdesignwasmadetoreducetheeffectofmemoryontheinnerwallofthesampleinletsystemsuitablefortheinvestigationofsemi-volatileorganiccompound.Inthiswavelengthrange,p-dichlorobenzenemoleculesfirstlyabsorbedonephotontobeexcitedfromthegToundstate~1A_g(S_0)tothefirstexcitedstate1B2u($1),thenabsorbedanotherphotontobeionized.Therelationshipbetweenthesignalintensityofp-dichlorobenzenemolecularionC_6H_4~(35)Cl_2~+at248-nmwavelengthandthelaserpowerwasgiven.The1.52powerindexofC_6H_4~(35)Cl_2~+wasatypicalidentificationofthe3/2powerlaw.TherelationshipbetweentheionsignalintensityofC_6H_4~(35)Cl_2~+andthesampleconcentrationwasclosetoalinearoneintheppm(V/V)range,whichledtoadetectionlimitof125ppb(V/V)forp-dichlorobenzene.