High energy density performance of hydrothermally produced hydrous ruthenium oxide/multiwalled carbon nanotubes composite: Design of an asymmetric supercapacitor with excellent cycle life

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摘要 Hydrousrutheniumoxide(h-RuO2)nanoparticlesanditscompositewithmultiwalledcarbonnanotubes(h-RuO2/MWCNT)weresynthesizedbyasimplehydrothermalmethodandprovedtohavepotentialapplicationashybridsupercapacitormaterial.Theh-RuO2andh-RuO2/MWCNTwerecharacterizedfortheirphysico-chemicalpropertiesbyPXRD,BETsurfacearea,Raman,SEM-EDSandTEMtechniques.Theelectrochemicalperformanceofthematerialswereinvestigated,specificcapacitance(Cs)ofh-RuO2andhRuO2/MWCNTestimatedbytheircyclicvoltammetricstudieswerefoundtobe604and1585F/grespectivelyatascanrateof2mV/sinthepotentialrange0–1.2V.Further,thisvaluewasfoundtobenearlythreetimeshigherthanthatofpureh-RuO2.Anasymmetricsupercapacitor(AS)devicewasfabricatedbyemployingh-RuO2/MWCNTasthepositiveelectrodeandactivatedcarbonasthenegativeelectrode.ThedeviceexhibitedCsof61.8F/gatascanrateof2mV/s.Further,thedeviceshowedexcellentlongtermstabilityfor20,000cycleswith88%capacitanceretentionatahighcurrentdensityof25A/g.
机构地区 不详
出处 《能源化学:英文版》 2016年4期
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出版日期 2016年04月14日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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