Characterization of Rust Layer Formed on Low alloy Steel Exposed in Marine Atmosphere

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摘要 TheironrustphasesformedonIowalloysteelscontainingdifferentquantitiesofCrelementhavebeencharacterizedusingEPMA,Ramanspectroscopy,TEM,opticalmicroscopyetc.Theionselectivepropertiesofsynthesizedrustfilmswiththesamephaseconstituentastheatmosphericcorrosionproductswereinvestigatedusingself-madeapparatus.TheresultsshowedthatcorrosionlossofsteelsexposedinmarineatmospheredecreasedrapidlyastheCrcontentofthesteelwasincreased.Cr-containingsteelswerecoveredbyauniformcompactedrustlayercomposedoffineparticleswithanaveragediameterofseveralnanometers.InnerrustlayerofCr-containingsteel(2massfraction)wascomposedofα-CrxFel-xOOH,withCrcontentofabout5massfraction.Suchrustlayershowedcationselectiveproperty,andcoulddepressthepenetrationofCl-tocontactsubstratesteeldirectly.
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出版日期 2002年05月15日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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