摘要
Theoxidationbehaviorofthreebiodieselsofdifferentorigins,viz.rapeseedoilderivedbiodiesel,soybeanoilderivedbiodieselandwasteoilbasedbiodiesel,weretestedonanoxidationtester.Thechemicalcompositionsofthebiodieselswerecharacterizedbygaschromatography.Thereafter,thestructuraltransformationoffattyacidmethylester(FAME)ofthebiodieselswasanalyzedbyaninfraredspectrometerandanultravioletabsorptionspectrometer.TheresultsdemonstratedthattheoxidationbehaviorofbiodieselsofdifferentoriginswascloselyrelatedtothecompositionanddistributionofFAMEs.HigherconcentrationofunsaturatedFAMEwithmulti-doublebondsexhibitedpooreroxidationresistance.Furthermore,cis-transisomerizationtransformationoccurredintheunsaturatedFAMEmoleculesandconjugateddouble-bondproducedduringtheoxidationprocessofbiodiesel.Greatercis-transvariationscorrespondedtodeeperoxidationdegree.ThehigherthecontentofunsaturatedFAMEwithmulti-doublebondsinabiodiesel,themoretheconjugateddoublebondswasformed.
出版日期
2013年03月13日(中国期刊网平台首次上网日期,不代表论文的发表时间)