Spectroscopic Analysis of Structural Transformation in Biodiesel Oxidation

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摘要 Theoxidationbehaviorofthreebiodieselsofdifferentorigins,viz.rapeseedoilderivedbiodiesel,soybeanoilderivedbiodieselandwasteoilbasedbiodiesel,weretestedonanoxidationtester.Thechemicalcompositionsofthebiodieselswerecharacterizedbygaschromatography.Thereafter,thestructuraltransformationoffattyacidmethylester(FAME)ofthebiodieselswasanalyzedbyaninfraredspectrometerandanultravioletabsorptionspectrometer.TheresultsdemonstratedthattheoxidationbehaviorofbiodieselsofdifferentoriginswascloselyrelatedtothecompositionanddistributionofFAMEs.HigherconcentrationofunsaturatedFAMEwithmulti-doublebondsexhibitedpooreroxidationresistance.Furthermore,cis-transisomerizationtransformationoccurredintheunsaturatedFAMEmoleculesandconjugateddouble-bondproducedduringtheoxidationprocessofbiodiesel.Greatercis-transvariationscorrespondedtodeeperoxidationdegree.ThehigherthecontentofunsaturatedFAMEwithmulti-doublebondsinabiodiesel,themoretheconjugateddoublebondswasformed.
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出版日期 2013年03月13日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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